This song is a great example of Reggae bass lines; it follows the chord progression, while playing with rhythms and syncopation. A lot of the bass notes are not on the strong beats, which makes them stand out in the mix. Note that the rhythm is in double swing, or swing of sixteenth notes.
The chord progression is pretty simple, it is in the key of G minor and it uses the chords i - iv - v - VI. The most important thing to focus on in this song is the rhythm of the notes.
I Shot the Sheriff - Bob Marley Bass Guitar
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